image: Researchers demonstrated that spray coating a rough layer of the negatively charged compound PCBM in a solar cell 'sandwich' gives the already-promising alternative to silicon-based solar cells, perovskite, new potential for low-cost mass production. The crystalline structure of perovskite was difficult to cover uniformly using prior deposition methods and substances. With the new method, the researchers reported a 30 percent improvement in power conversion efficiency versus other coatings, applied by spin casting. view more
Credit: "Yifan Zheng et al., <i>Nanoscale</i>, 2018, DOI: 10.1039/C8NR01763H" with permission from the Royal Society of Chemistry
BROOKLYN, New York, Thursday, June 21, 2018 - An international team of university researchers today reports solving a major fabrication challenge for perovskite cells -- the intriguing potential challengers to silicon-based solar cells.
These crystalline structures show great promise because they can absorb almost all wavelengths of light. Perovskite solar cells are already commercialized on a small scale, but recent vast improvements in their power conversion efficiency (PCE) are driving interest in using them as low-cost alternatives for solar panels.In the cover article published online today for the June 28, 2018 issue of Nanoscale, a publication of the Royal Society of Chemistry, the research team reveals a new scalable means of applying a critical component to perovskite cells to solve some major fabrication challenges. The researchers were able to apply the critical electron transport layer (ETL) in perovskite photovoltaic cells in a new way -- spray coating -- to imbue the ETL with superior conductivity and a strong interface with its neighbor, the perovskite layer.
The research is led by André D. Taylor, an associate professor in the NYU Tandon School of Engineering's Chemical and Biomolecular Engineering Department, with Yifan Zheng, the first author on the paper and a Peking University researcher. Co-authors are from the University of Electronic Science and Technology of China, Yale University, and Johns Hopkins University.
Most solar cells are "sandwiches" of materials layered in such a way that when light hits the cell's surface, it excites electrons in negatively charged material and sets up an electric current by moving the electrons toward a latticework of positively charged "holes." In perovskite solar cells with a simple planar orientation called p-i-n (or n-i-p when inverted), the perovskite constitutes the light-trapping intrinsic layer (the "i" in p-i-n) between the negatively charged ETL and a positively charged hole transport layer (HTL).
When the positively and negatively charged layers are separated, the architecture behaves like a subatomic game of Pachinko in which photons from a light source dislodge unstable electrons from the ETL, causing them to fall toward the positive HTL side of the sandwich. The perovskite layer expedites this flow. While perovskite makes for an ideal intrinsic layer because of its strong affinity both for holes and electrons and its quick reaction time, commercial-scale fabrication has proved challenging partly because it is difficult to effectively apply a uniform ETL layer over the crystalline surface of the perovskite.
The researchers chose the compound [6,6]-phenyl-C(61)-butyric acid methyl ester (PCBM) because of its track record as an ETL material and because PCBM applied in a rough layer offers the possibility of improved conductivity, less-penetrable interface contact, and enhanced light trapping. "Very little research has been done on ETL options for the planar p-i-n design," said Taylor. "The key challenge in planar cells is, how do you actually assemble them in a way that doesn't destroy the adjacent layers?"
The most common method is spin casting, which involves spinning the cell and allowing centripetal force to disperse the ETL fluid over the perovskite substrate. But this technique is limited to small surfaces and results in an inconsistent layer that lowers the performance of the solar cell. Spin casting is also inimicable to commercial production of large solar panels by such methods as roll-to-roll manufacture, for which the flexible p-i-n planar perovskite architecture is otherwise well suited.
The researchers instead turned to spray coating, which applies the ETL uniformly across a large area and is suitable for manufacturing large solar panels. They reported a 30 percent efficiency gain over other ETLs - from a PCE of 13 percent to over 17 percent - and fewer defects. Added Taylor, "Our approach is concise, highly reproducible, and scalable. It suggests that spray coating the PCBM ETL could have broad appeal toward improving the efficiency baseline of perovskite solar cells and providing an ideal platform for record-breaking p-i-n perovskite solar cells in the near future."
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The Foundation of the National Natural Science Foundation of China (NSFC), the Foundation for Innovation Research Groups of the NSFC, the Chinese Scholarship Council, and the U.S. National Science Foundation provided funding for the study.
"Spray Coating of the PCBM Electron Transport Layer Significantly Improves the Efficiency of p-i-n Planar Perovskite Solar Cells" is at http://pubs.rsc.org/en/content/articlelanding/2018/nr/c8nr01763h#!divAbstract.
About the New York University Tandon School of Engineering
The NYU Tandon School of Engineering dates to 1854, the founding date for both the New York University School of Civil Engineering and Architecture and the Brooklyn Collegiate and Polytechnic Institute (widely known as Brooklyn Poly). A January 2014 merger created a comprehensive school of education and research in engineering and applied sciences, rooted in a tradition of invention and entrepreneurship and dedicated to furthering technology in service to society. In addition to its main location in Brooklyn, NYU Tandon collaborates with other schools within NYU, one of the country's foremost private research universities, and is closely connected to engineering programs at NYU Abu Dhabi and NYU Shanghai. It operates Future Labs focused on start-up businesses in downtown Manhattan and Brooklyn and an award-winning online graduate program. For more information, visit http://engineering.nyu.edu.
Journal
Nanoscale