Carbon-based supports for electrocatalysis under industrially relevant conditions

This review is led by Prof. Wei Lin (SINOPEC Research Institute of Petroleum Processing) and Prof. Lichen Liu (Department of Chemistry, Tsinghua University). Carbon materials, due to their appropriate physicochemical characteristics such as high surface area, adjustable pore structure, variable morphology, and multifunctional surface properties based on chemical modifications, low cost, and ease of preparation from various precursors, are ideal carrier materials for functional metal components. Particularly in electrochemical systems (such as proton exchange membrane fuel cells, PEMFC, and proton exchange membrane water electrolysis, PEMWE), carbon materials play a vital role because they can serve as conductive carriers for active metal components. However, in the rapidly growing literature in the field of electrocatalysis, most studies typically focus on functional metal or metal oxide components supported on commercial carbon. The role of carbon materials as supports and their impact on catalytic performance have not received sufficient attention, warranting more research efforts from both academia and industry.

Recently, Prof. Wei Lin and Prof. Lichen Liu have attempted to approach from an industrial perspective, discussing key parameters that can be directly measured or studied in experiments to reveal the synthesis-structure-performance relationship. The paper systematically introduces and explains the application of carbon carrier materials in the electrochemical field under industrially relevant conditions and the existing challenges and future breakthrough directions from six aspects: electrochemical conductivity, chemical composition, stability under industrial conditions, mass transfer, bulk synthesis, and in-depth understanding. Finally, based on their knowledge and experience accumulated in industrial R&D activities, the authors propose the following critical standards that carbon supports in practical electrocatalytic devices need to meet: (1) specific surface area > 60 m²/g; (2) electrical resistivity <2.5 Ω·m; (3) primary carbon particle size < 50 nm; (4) recyclability over 5000 cycles (at 1.0-1.5V); (5) cost below $4000/ton. Specifically, the authors also suggest a primary carbon particle size < 50 nm, as smaller particles can improve conductivity and viscosity, enhance weather resistance, provide better reinforcement, increase tensile strength, and abrasion resistance. Additionally, smaller particle size is correlated with a greater specific surface area, facilitating dense platinum loading and the construction of thin catalyst layers. These key indicators can serve as guiding parameters for the development of advanced carbon carriers for PEMFC and PEMWE devices. The first author of the paper is Dr. Xue Yang from Sinopec Research Institute of Petroleum Processing, and the corresponding authors are Prof. Wei Lin and Prof. Lichen Liu

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Carbon-based supports for electrocatalysis under industrially relevant conditions

https://doi.org/10.1007/s11426-022-1342-4