Entire color palette of inexpensive fluorescent dyes

Novel fluorescent dyes developed by ETH researchers are relatively simple and inexpensive to produce. The dyes are polymers with a modular structure. They consist of a different number of subunits depending on their colour. The subunits used are chemically simple molecules that are either commercially available or can be produced by chemists in one reaction step.

Now, scientists led by Yinyin Bao have succeeded in using the new approach to produce a wide range of colours, including red, which was previously difficult to produce. Bao is a senior scientist in the groups of ETH professors Jean-Christophe Leroux and Chih-Jen Shih. Together with scientists from RMIT University in Melbourne, the team developed artificial intelligence algorithms that help decide which molecule subunits are needed in what numbers for a particular colour.

Potential applications for the fluorescent inks include UV-activated security inks for banknotes, certificates, passports or for encrypting information. The method can also be used to produce inks that change colour after prolonged UV illumination. In their new work, which the scientists published in the scientific journal Chem, they demonstrated this using the example of two initially red fluorescent inks, one of which turns blue after several minutes of UV illumination, while the other remains red. This property can also be used for security features.

Other applications for the new fluorescent molecules are in solar power plants, or they could one day be combined with semiconducting molecules to produce low-cost organic light-emitting diodes (OLEDs) for displays.

Reference

Ye S, Meftahi N, Lyskov I, Tian T, Kumar S, Christofferson AJ, Winkler DA, Shih CJ, Russo S, Leroux JC, Bao Y: Machine Learning-Assisted Exploration of a Versatile Polymer Platform with Charge Transfer-Dependent Full-Color Emission, Chem 2 January 2023

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