image: Sample of material developed at NYU Tandon comprising perfluorinated sulfonic acid ionomer. One part of the copolymer conducts ions, and the other is highly permeable to oxygen, a dual benefit to hydrogen fuel cells. view more
Credit: NYU Tandon School of Engineering
Renewed investments in hydrogen fuel cell technologies and infrastructure by companies like Amazon; nations like China; and automakers like Toyota, Honda, and Hyundai, are sparking sales and fresh interest in the vast possibilities of polymer-electrolyte fuel cells. The fresh interest could revolutionize transportation and fill streets with vehicles whose only effluent is water vapor.
But that vision of clean, green cars and trucks is stymied by the need not only for massive infrastructure investment, but for more efficient processes in the cells themselves. Innovations that lower the cost of production -- meaning lower sticker price -- and that open the door to more vehicle segments, including performance cars, could drive greater adoption.
A team of researchers at the NYU Tandon School of Engineering, led by Miguel Modestino, professor of chemical and biomolecular engineering, and Lawrence Berkeley National Laboratory has created a novel polymeric material with the potential for solving both problems.
The research, "Highly Permeable Perfluorinated Sulfonic Acid Ionomers for Improved Electrochemical Devices: Insights into Structure - Property Relationships," published in the Journal of the American Chemical Society, focuses on a hybrid material that delivers copious amounts of oxygen from the atmosphere to the cell's electrode reaction sites -- generating more power -- while reducing the amount of expensive materials like platinum needed in fuel cells, potentially solving a major industry challenge.
Hydrogen fuel cells comprise an anode and a cathode, with an electrolyte membrane between them. Electricity is produced in a process whereby hydrogen reacts in the anode and atmospheric oxygen in the cathode. At the latter site, protons combine with oxygen to produce electricity and water. Ion-conducting polymers (ionomers) are used to bring the protons to the reaction sites where oxygen from air needs to permeate through them to drive the electricity-generating reaction.
Current, commercially available ionomers are typically perfluorinated sulfonic acid (PFSA) polymers that comprise a linear chainlike backbone composed of polytetrafluoroethylene (PTFE) matrix, and pendant sulfonic-acid groups attached to the PTFE backbone that impart ion conductivity. While this complex combination, molecularly similar to Teflon, confers high mechanical strength, research shows that it suffers from low oxygen permeability, leading to significant energy losses fuel cells.
The researchers -- including Yoshi Okamoto, a professor of chemical engineering and director of the Polymer Research Institute at NYU Tandon, and Ph.D. student Adlai Katzenberg, who did the research as part of a U.S. Department of Energy fellowship -- solved several problems at once by swapping the linear PTFE polymer chains with a bulky fluorinated chain, which added more free volume to the matrix, vastly enhancing its ability to transport oxygen in fuel cells.
Modestino explains that the hybrid material comprises an ion conducting polymer and a highly permeable matrix. "We've created a novel copolymer -- two components bound together. One part conducts ions, and the other is highly permeable to oxygen," he says. "Okamoto had been working on highly permeable polymers for gas separation processes. When I joined NYU Tandon, we realized that the polymers that he had developed could be adapted to improve fuel cells."
###
This research was supported by a grant from United States Department of Energy.
"Highly Permeable Perfluorinated Sulfonic Acid Ionomers for Improved Electrochemical Devices: Insights into Structure - Property Relationships" is available at https://pubs.acs.org/doi/10.1021/jacs.9b09170
About the New York University Tandon School of Engineering
The NYU Tandon School of Engineering dates to 1854, the founding date for both the New York University School of Civil Engineering and Architecture and the Brooklyn Collegiate and Polytechnic Institute (widely known as Brooklyn Poly). A January 2014 merger created a comprehensive school of education and research in engineering and applied sciences, rooted in a tradition of invention and entrepreneurship and dedicated to furthering technology in service to society. In addition to its main location in Brooklyn, NYU Tandon collaborates with other schools within NYU, one of the country's foremost private research universities, and is closely connected to engineering programs at NYU Abu Dhabi and NYU Shanghai. It operates Future Labs focused on start-up businesses in downtown Manhattan and Brooklyn and an award-winning online graduate program. For more information, visit http://engineering.nyu.edu.
Journal
Journal of the American Chemical Society