image: This is a custom chamber built by researchers at Rice University allowed them to refine their process for creating laser-induced graphene. view more
Credit: Tour Group/Rice University
HOUSTON - (May 15, 2017) - Rice University scientists who invented laser-induced graphene (LIG) for applications like supercapacitors have now figured out a way to make the spongy graphene either superhydrophobic or superhydrophilic.
And it's a gas.
Until recently, the Rice lab of James Tour made LIG only in open air, using a laser to burn part of the way through a flexible polyimide sheet to get interconnected flakes of graphene. But putting the polymer in a closed environment with various gases changed the product's properties.
Forming LIG in argon or hydrogen makes it superhydrophobic, or water-avoiding, a property highly valued for separating water from oil or de-icing surfaces. Forming it in oxygen or air makes it superhydrophilic, or water-attracting, and that makes it highly soluble.
The research at Rice and at Ben-Gurion University in Israel is the subject of a paper in Advanced Materials.
"Labs could make graphene either hydrophobic or hydrophilic before, but it involved multiple steps of either wet-chemical or chemical vapor deposition processes," Tour said. "We're doing this in one step with relatively cheap materials in a homemade atmosphere chamber."
The labs got a bonus when they discovered that fabricating LIG in oxygen increased the number of defects -- 5- and 7-atom rings -- in the graphene flakes, improving its capacitance and its performance when used as an electrode material for microsupercapacitors.
Changes in the chemical content of the gas and even changes in the direction of the laser raster pattern altered the material, leading the researchers to believe LIG's hydrophobic or -philic properties could be tuned.
They also discovered when they scraped graphene off of a hydrophilic sheet of polymer and turned it into a film, the result was hydrophobic instead. "That leads us to believe the surface orientation of LIG's flakes have a lot to do with how it reacts with water," Tour said. "If the edges are more exposed, it appears to be hydrophilic; if the basal planes are more exposed, their hydrophobic properties take over."
What makes a material "super" in either direction is the angle at which it encounters water. A material with a contact angle of 0 degrees is considered superhydrophilic. In this case, water would lay on the material in a puddle. If the angle is 150 degrees or more, that's superhydrophobic; the angle is determined by how much the water beads. (An angle of 180 degrees would be a sphere sitting perfectly on top of LIG.)
The discovery that surface type and chemistry affect LIG should also allow some leeway in adjusting the material's properties, Tour said. In fact, when they used a sulfur/fluorine gas to make it, they raised LIG's superhydrophobicity to 160 degrees.
###
Yilun Li, a graduate student at Rice, is lead author of the paper. Co-authors are Rice graduate students Duy Xuan Luong and Jibo Zhang, undergraduate Yash Tarkunde, research scientist Carter Kittrell and former postdoctoral researcher Yongsung Ji; and graduate student Franklin Sargunaraj and co-principal investigator Christopher Arnusch, a lecturer at the Zuckerberg Institute for Water Research at Ben Gurion University of the Negev, Israel. Tour is the T.T. and W.F. Chao Chair in Chemistry as well as a professor of computer science and of materials science and nanoengineering at Rice.
The Air Force Office of Scientific Research and its Multidisciplinary University Research Initiative and the Vietnam Education Foundation supported the research.
Read the abstract at http://dx.doi.org/10.1002/adma.201700496
This news release can be found online at http://news.rice.edu/2017/05/15/gas-gives-laser-induced-graphene-super-properties-2/
Follow Rice News and Media Relations via Twitter @RiceUNews
Videos:
https://www.youtube.com/watch?v=_xFBDkQH7GA
Water rolls off a superhydrophilic laser-induced graphene pattern placed inside a superhydrophobic LIG frame. (Credit: Tour Group/Rice University)
https://www.youtube.com/watch?v=qAuyVgYI9m8
A water droplet bounces on the surface of laser-induced graphene with a sulfur and fluorine gas in the chamber. (Credit: Tour Group/Rice University)
Related materials:
Rice University's laser-induced graphene makes simple, powerful energy storage possible: https://youtu.be/NqIa5j0Oo9E
Tour Group: http://www.jmtour.com
Arnusch Laboratory: http://arnuschlab.weebly.com
Wiess School of Natural Sciences: http://natsci.rice.edu
Images for download:
http://news.rice.edu/files/2017/04/0424_LIG-1-web-1w2w8p0.jpeg
Laser-induced graphene created in the presence of argon gas is superhydrophobic, meaning it avoids water. The process developed at Rice University makes materials that can be superhydrophilic or superhydrophobic from inexpensive materials and in one step. (Credit: Tour Group/Rice University)
http://news.rice.edu/files/2017/04/0424_LIG-6-web-2ho6xbi.jpg
Superhydrophobic (water-avoiding) laser-induced graphene created in the presence of argon gas could be useful for de-icing applications or separating water and oil. (Credit: Tour Group/Rice University)
http://news.rice.edu/files/2017/04/0424_LIG-4-web-1mmeudq.jpeg
A custom chamber built by researchers at Rice University allowed them to refine their process for creating laser-induced graphene. (Credit: Tour Group/Rice University)
http://news.rice.edu/files/2017/04/0424_LIG-5-web-2bfney5.jpg
A custom-built chamber allows Rice University researchers to grow laser-induced graphene in various environments. The laser is fired at polymer through the zinc-selenium window. (Credit: Tour Group/Rice University)
Located on a 300-acre forested campus in Houston, Rice University is consistently ranked among the nation's top 20 universities by U.S. News & World Report. Rice has highly respected schools of Architecture, Business, Continuing Studies, Engineering, Humanities, Music, Natural Sciences and Social Sciences and is home to the Baker Institute for Public Policy. With 3,879 undergraduates and 2,861 graduate students, Rice's undergraduate student-to-faculty ratio is 6-to-1. Its residential college system builds close-knit communities and lifelong friendships, just one reason why Rice is ranked No. 1 for happiest students and for lots of race/class interaction by the Princeton Review. Rice is also rated as a best value among private universities by Kiplinger's Personal Finance. To read "What they're saying about Rice," go to http://tinyurl.com/RiceUniversityoverview.
Journal
Advanced Materials