image: The green smart tag on the bottle above indicates that the product is no longer fresh. The image is a screenshot of a video: http://www.youtube.com/watch?v=y-Fpj9bdht4. view more
Credit: Chao Zhang, Ph.D.
DALLAS, March 17, 2014 — A color-coded smart tag could tell consumers whether a carton of milk has turned sour or a can of green beans has spoiled without opening the containers, according to researchers. The tag, which would appear on the packaging, also could be used to determine if medications and other perishable products were still active or fresh, they said.
This report on the color-changing food deterioration tags was presented today as part of the 247th National Meeting & Exposition of the American Chemical Society (ACS), the world's largest scientific society. A new video, illustrating how the tag works, is available at http://www.youtube.com/watch?v=y-Fpj9bdht4.
The meeting, attended by thousands of scientists, features more than 10,000 reports on new advances in science and other topics. It is being held at the Dallas Convention Center and area hotels through Thursday.
"This tag, which has a gel-like consistency, is really inexpensive and safe, and can be widely programmed to mimic almost all ambient-temperature deterioration processes in foods," said Chao Zhang, Ph.D., the lead researcher of the study. Use of the tags could potentially solve the problem of knowing how fresh packaged, perishable foods remain over time, he added. And a real advantage, Zhang said, is that even when manufacturers, grocery-store owners and consumers do not know if the food has been unduly exposed to higher temperatures, which could cause unexpected spoilage, "the tag still gives a reliable indication of the quality of the product."
The tags, which are about the size of a kernel of corn, would appear in various color codes on packaging. "In our configuration, red, or reddish orange, would mean fresh," explained Zhang, who is at Peking University in Beijing, China. "Over time, the tag changes its color to orange, yellow and later green, which indicates the food is spoiled." The colors signify a range between 100 percent fresh and 100 percent spoiled. For example, if the label says that the product should remain fresh for 14 days under refrigeration, but the tag is now orange, it means that the product is only roughly half as fresh. In that case, the consumer would know the product is edible for only another seven days if kept refrigerated, he explained.
The researchers developed and tested the tags using E. coli (food-spoiling bacteria that cause gastrointestinal problems) in milk as a reference model. "We successfully synchronized, at multiple temperatures, the chemical evolution process in the smart tag with microbial growth processes in the milk," according to Zhang. The tags could also be customized for a variety of other foods and beverages.
The tags contain tiny metallic nanorods that, at different stages and phases, can have a variety of colors: red, orange, yellow, green, blue and violet, Zhang explained. "The gold nanorods we used are inherently red, which dictates the initial tag color," he said. "Silver chloride and vitamin C are also in the tags, reacting slowly and controllably. Over time, the metallic silver gradually deposits on each gold nanorod, forming a silver shell layer. That changes the particle's chemical composition and shape, so the tag color now would be different. Therefore, as the silver layer thickens over time, the tag color evolves from the initial red to orange, yellow, and green, and even blue and violet."
Although the nanorods are made of gold and silver, a tag would still be very inexpensive, and all the chemicals in the tiny tag cost much less than one cent — $0.002. "In addition, all of the reagents in the tags are nontoxic, and some of them (such as vitamin C, acetic acid, lactic acid and agar) are even edible," he explained.
This technique has been patented in China, and some preliminary results have been published in ACS Nano, Zhang said. He added that the next step is to contact manufacturers and explain how the tag would be useful for them and their customers.
A press conference on this topic will be held Monday, March 17, at 3:00 p.m. Central time in Room A122/A123 of the Dallas Convention Center. Reporters can attend in person or access live video of the event and ask questions at the ACS Ustream channel http://www.ustream.tv/channel/acslive.
The study was supported by National Natural Science Foundation of China, Hong Kong Research Grants Council and National Basic Research Program of China.
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Title
Self-evolving color-changing smart tags capable of quality indication for perishable products
Abstract
The quality of perishable products (such as foods, beverages, pharmaceuticals and cosmetics) strongly depends on their temperature history. Temperature abuses during the custody chain may lead to significant quality degradation, which, however, is usually not directly visible to customers. Here we developed a self-evolving color-changing smart tag to track, mimic and indicate the deteriorative processes in common perishables. The smart tag exploits the chronochromic behaviors during the Ag overgrowth on Au nanorods in aqueous solution. Under given conditions, the smart tag spontaneously changes its appearance from an initial red to a final green color, exhibiting sharp visual contrast. At room temperature, the temporal duration for this red-to-green self-evolution can be adjusted from minutes to months, and the apparent activation energy can be widely tuned from 50 to 190 kJ/mol, covering the kinetic features of almost all ambient-temperature deteriorative processes found in foods. Using E. coligrowth in milk as a model, we successfully synchronized, at multiple temperatures, the chemical evolution process in the smart tag with the microbial growth processes, implying that the "bio-chemo" correlation is temperature-independent. The smart tag is also cost-effective and eco-friendly, and well meets the ASSURED criteria (Affordable, Sensitive, Specific, User-friendly, Robust and rapid, Equipment-free, and Deliverable to end-users) proposed by WHO. We believe that this smart tag holds the promise to be further developed into a standardized protocol for the current food/beverage/pharmaceutical industries.