image: a, Optical images of transparency-controlled microwire embedded polymer composite films in a freestanding form; Visible transparency of I = ~ 50 %, II = ~ 40 %, III= ~25 % and IV= ~ 10 %. b, The representation of the color coordinates of transparent solar cells in this study, verifying the neutral-colour transparency c, The electric field intensity in the microwires which can manipulate the light absorption. d, Light J-V characteristics The transparent solar cell based on the freestanding film with advanced light-absorption technique: the visible transparency of each device is I = ~ 50 %, II = ~ 40 %, III= ~25 % and IV = ~ 10 %. e, Schematic of the transparent solar cell based on the freestanding film, p-type polymer is in the top portion of and transparent conductive film is at the bottom. f, Light J-V curves of transparent solar cells under the bending state with the different bending radius. view more
Credit: by Sung Bum Kang, Ji-Hwan Kim, Myeong Hoon Jeong, Amit Sanger, Chan Ul Kim, Chil-Min Kim and Kyoung Jin Choi
TSCs are emerging devices that combine the advantages of visible transparency and light-to-electricity conversion. One of the valuable prospective applications of such devices is their integration into buildings, vehicles, or portable electronics. Therefore, colour-perception and flexibility are important as well as the efficiency. Currently, existing transparent solar cells are based predominantly on organics, dyes, perovskites and amorphous Si; however, the colour-tinted transparent nature or rigidity of those devices strongly limits the utility of the resulting TSCs for real-world applications.
In a new paper published in Light Science & Application, scientists from Department of Materials Science and Engineering, Ulsan National Institute of Science and Technology, Republic of Korea and co-workers developed flexible and efficient transparent solar cells which have colour-neutrality. Based on the silicon microwires embedded in the transparent polymer matrix, they demonstrated transparent, flexible and even stretchable solar cells. This freestanding film was successfully utilized for building block of transparent solar cells. A heterojunction between n-type Si and p-type polymeric semiconductor is formed at the top portion and a transparent conductive film at the bottom of the device. The transparency of the devices can be tuned from ~ 10% to 55% by adjusting the spacing between the microwires. Moreover, after the cyclic bending test or under the bending state, the performance was maintained without a significant decrease. indicating that the transparent solar cells have excellent flexibility. This stretchable and transparent freestanding-form of microwire array / polymer composites film in this study is promising for future transparent solar cells.
Transparent solar cells have an unavoidable trade-off between the energy generation and the light admission. Therefore, based on the criteria for transparent solar cells, there is an inevitable compromise of the efficiency to achieve transparency. This makes transparent solar cells difficult to get high performance. Overcoming this issue, these scientists suggest their strategy to obtain high performance transparent solar cells:
"Basically, the solar cells can generate the electricity from the absorbed light. Therefore, attaining the high performance as maintaining the transparency is very challenging. We revealed absorption mechanism inside Si microwire-array and developed the new morphology of microwire which can manipulate the path of light. As a result, we successfully enhanced light absorption which can contribute to the light-generated-current in the transparent solar cells maintaining the transparency"
"The transparent solar cell based on the freestanding film with advanced light-absorption technique shows the power conversion efficiency over 8 % at 10 % of visible transparency, which are comparable to state-of-the-art neutral-colour transparent solar cells based on organics and perovskites." they added.
"Moreover, the devices are based on the Si wafer already verified and widely used in the Si solar cell market. Therefore, this robust, ultra-light and flexible platform is feasible and promising as a commercialized transparent solar cell for practical application in the future" the scientists forecast.
###