image: (a) Schematic illustration of synthesis procedure for Ru@Zn-SAs/N-C catalysts, where the electrostatic potential diagram of the iso-surface value is 0.03 e Å-3; (b-d) SEM images with different magnification; (e) TEM image; (f-g) HRTEM images, (f) the inset is the corresponding particle-size distribution of Ru clusters and (g) the inset shows the Moiré images extracted from the FFT; (h) AC HADDF-STEM image and integrated pixel intensities; (i) AFM image and corresponding height profiles of Ru@Zn-SAs/N-C.
Credit: Hao Li et al.
As the world moves toward sustainable energy, hydrogen will likely play an invaluable role as a clean and versatile fuel. Yet, adoption of hydrogen technologies hinges on overcoming key challenges in electrocatalysis, where costly and scarce platinum-group metals have long been the industry standard. Taking one step to rectify this, a research team has now developed a new strategy that fine-tunes electronic interactions at the atomic level.
The study introduces an innovative electronic fine-tuning (EFT) approach to enhance the interactions between zinc (Zn) and ruthenium (Ru) species, resulting in a highly active and stable catalyst for both the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER). By anchoring Ru clusters onto hierarchically layered Zn-N-C nanosheets (denoted as Ru@Zn-SAs/N-C), the team has designed a material that outperforms commercial platinum-based catalysts.
"Our work demonstrates how precise control over electronic structures can fundamentally reshape catalytic performance," says Hao Li, associate professor at Tohoku University's Advanced Institute for Materials Research (WPI-AIMR) and corresponding author of the paper. "By leveraging the synergy between Zn and Ru, we have developed a cost-effective alternative to conventional platinum catalysts, offering new possibilities for sustainable hydrogen production."
Key to this breakthrough is the strong electronic metal-support interaction (EMSI) between Zn and Ru, which optimizes the adsorption energy of critical reaction intermediates. X-ray absorption spectroscopy and computational modeling confirm that this synergy shifts *OOH and *OH adsorption energies to an optimal balance, enhancing ORR efficiency. Simultaneously, Ru sites achieve near-ideal hydrogen binding free energy, placing the catalyst at the peak of theoretical HER activity.
"This research is not just about replacing platinum," Li explains. "It's about understanding how electronic properties at the atomic level dictate catalytic efficiency. That knowledge allows us to design better, more accessible materials for real-world applications."
These findings have significant implications for the affordability and scalability of hydrogen energy. By reducing dependence on expensive platinum while improving performance, this research contributes to the development of cost-effective hydrogen fuel cells, water electrolysis systems, and sustainable industrial processes.
Looking ahead, the team plans to further refine the EFT strategy, improve catalyst stability under real-world conditions, and develop scalable production methods. Applications in zinc-air batteries, fuel cells, and carbon and nitrogen reduction reactions are also under investigation.
The research has been made available through the Digital Catalysis Platform (DigCat), the largest experimental catalysis database to date, developed by the Hao Li Lab.
Details of its findings were published in the journal Advanced Functional Materials. The article processing charge (APC) was supported by the Tohoku University Support Program.
About the World Premier International Research Center Initiative (WPI)
The WPI program was launched in 2007 by Japan's Ministry of Education, Culture, Sports, Science and Technology (MEXT) to foster globally visible research centers boasting the highest standards and outstanding research environments. Numbering more than a dozen and operating at institutions throughout the country, these centers are given a high degree of autonomy, allowing them to engage in innovative modes of management and research. The program is administered by the Japan Society for the Promotion of Science (JSPS).
See the latest research news from the centers at the WPI News Portal: https://www.eurekalert.org/newsportal/WPI
Main WPI program site: www.jsps.go.jp/english/e-toplevel
Advanced Institute for Materials Research (AIMR)
Tohoku University
Establishing a World-Leading Research Center for Materials Science
AIMR aims to contribute to society through its actions as a world-leading research center for materials science and push the boundaries of research frontiers. To this end, the institute gathers excellent researchers in the fields of physics, chemistry, materials science, engineering, and mathematics and provides a world-class research environment.
Journal
Advanced Functional Materials
Article Publication Date
23-Dec-2024