New insights into bonding nature of antimony – implications for materials research

The study combined experimental measurements with theoretical calculations, with the aim of analysing the nature and strength of the chemical bonding in antimony. “The strength of a bond depends directly on the distance between the atoms,” says Professor Claudia S. Schnohr of the Felix Bloch Institute for Solid State Physics at Leipzig University, adding that comparisons with other materials such as metals and semiconductors show that this distance dependence is characteristic of the type of chemical bond.

Of particular note is the demonstrably smooth transition between classical covalent bonding and electron-rich multi-centre bonding. Covalent bonding is seen, for example, in semiconductors such as germanium. “Our results show that antimony in its stable phase exhibits characteristics of both types of bonding,” says co-author Professor Oliver Oeckler of the Institute of Inorganic Chemistry and Crystallography at Leipzig University. This has important implications for the understanding of phase change materials, which are used in data storage and thermoelectrics, among other applications.

Antimony as a model for phase change materials

“We investigated antimony as an elemental model system for phase change materials. It has a similar structure to germanium telluride, but consists of only one type of atom,” says Professor Claudia Schnohr. These properties facilitate analysis and comparison with other materials to better understand their bonding characteristics.

The findings could be used to optimise material properties. “In the future, the experimental or theoretical determination of force constants will make it possible to tailor the design of new materials,” says Schnohr. This could be particularly useful for applications in electronic storage media and thermoelectrics.