The pursuit of clean, sustainable energy has driven researchers to explore innovative materials and processes. However, a major hurdle in the development of advanced energy storage devices, such as fuel cells and metal-air batteries, is sluggish oxygen reduction reaction (ORR). While platinum-based catalysts have traditionally dominated the field, their high cost and scarcity warrant the need for more affordable and abundant alternatives.
To that end, a group of researchers at East China University of Science and Technology (ECUST), led by Professor Jin-Gang Liu, developed a novel, high-performance catalyst derived from sustainable biomass. Their findings are published in the KeAi journal Green Energy & Environment.
The team's approach involves utilizing carboxymethylcellulose (CMC), a readily available biomass material, as the foundation for the catalyst.
“By combining CMC with iron and phosphorus, we created a unique structure with "Fe-N3P" active sites,” shares Liu. “This structure enhances catalytic activity by facilitating the removal of key reaction intermediates, ultimately boosting ORR efficiency.”
The researchers compared their biomass-derived catalyst (FeNPC) to traditional options and found it to outperform them significantly in both alkaline solutions and zinc-air batteries. FeNPC exhibited superior activity, stability and power density, making it a potential candidate for real-world applications.
“One of the most notable aspects of this research is the use of biomass as a starting material. This approach not only reduces reliance on limited resources, but also aligns with the principles of a circular economy, encouraging further exploration of biomass-derived catalysts for various clean energy applications,” says Liu.
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Contact the author: Jin-Gang Liu, Key Laboratory for Advanced Materials, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China, E-mail: liujingang@ecust.edu.cn.
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Journal
Green Energy & Environment
Article Title
Biomass-derived single atom catalysts with phosphorus-coordinated Fe-N3P configuration for efficient oxygen reduction reaction
COI Statement
There are no conflicts to declare.