Innovative copper-based catalyst paves the way for sustainable ammonia production

Ammonia plays a critical role in food production and industrial development, with a global market size of approximately 175 million tonnes and a market value of $67 billion. Likewise, it is a high-energy-density carrier, making it a key player in the emerging hydrogen economy. The downside to current ammonia production, however, is that synthesis relies heavily on the Harber-Bosch process, which is energy intensive, and results in large CO₂ emissions.

Yet, a research group led by Hao Li from Tohoku University's Advanced Institute for Materials Research (WPI-AIMR) has focused on the electrochemical conversion of nitrate (No₃^-) to ammonia (NH₃), unveiling a process that could potentially revolutionize industrial practices whilst offering new insights into the development of efficient and sustainable catalytic processes.

Details of the findings were published in the journal Advanced Science on August 9, 2024.

Unlike the nitrogen reduction reaction (NRR), which requires breaking the strong N=N triple bond in nitrogen (N₂), nitrate reduction (NO₃RR) offers a more efficient pathway," points out Li. "Nitrate has a much lower dissociation energy and higher solubility in water, making it easier to use as a nitrogen source for ammonia production. This not only enhances the efficiency of the process but also addresses the environmental challenge of nitrate accumulation in water systems.

Li and his team synthesized a spherical copper (II) oxide (CuO) catalyst, characterized by the stacking of small particles with oxygen -rich vacancies. This catalyst demonstrated a significant enhancement in ammonia yield, achieving 15.53 mg h^-1 mgcat^-1, with a Faraday efficiency of 90.69% in a neutral electrolyte at a voltage of -0.80 V (vs. reversible hydrogen electrode). Also revealed was that the high catalytic activity of the CuO electrodes stems from both structural and phase changes that occur during the electrochemical reduction process.

"Our research indicates that the transformation of CuO to a Cu/Cu(OH)₂ structure during the reaction process is key to the catalyst's performance," said Qiuling Jiang, a joint PhD student at WPI-AIMR and co-author of the paper. "This phase change not only increases the number of active sites but also improves electron transfer at the electrode surface, enhancing the efficiency of the nitrate reduction reaction."

Moreover, the study utilized density functional theory (DFT) calculations to further understand the catalytic mechanism. These calculations showed that the formation of Cu(OH)₂ reduces the energy barrier for nitrate adsorption, making the process energetically favorable. Additionally, the Cu(OH)₂ phase was found to inhibit the competing hydrogen evolution reaction, while the presence of Cu (111) crystal surfaces facilitated the hydrogenation process.

About the World Premier International Research Center Initiative (WPI)

The WPI program was launched in 2007 by Japan's Ministry of Education, Culture, Sports, Science and Technology (MEXT) to foster globally visible research centers boasting the highest standards and outstanding research environments. Numbering more than a dozen and operating at institutions throughout the country, these centers are given a high degree of autonomy, allowing them to engage in innovative modes of management and research. The program is administered by the Japan Society for the Promotion of Science (JSPS).

See the latest research news from the centers at the WPI News Portal: https://www.eurekalert.org/newsportal/WPI
Main WPI program site:  www.jsps.go.jp/english/e-toplevel

Advanced Institute for Materials Research (AIMR)
Tohoku University
Establishing a World-Leading Research Center for Materials Science
AIMR aims to contribute to society through its actions as a world-leading research center for materials science and push the boundaries of research frontiers. To this end, the institute gathers excellent researchers in the fields of physics, chemistry, materials science, engineering, and mathematics and provides a world-class research environment.