How can surface morphology change selectivity in electrocatalysis?

Catalysis plays a pivotal role in the chemical industry, significantly influencing numerous facets of everyday life such as plastic generation, drug development, and the manufacture of fertilizers. Heterogeneous electrocatalysis, in particular, is at the heart of developing sustainable energy technologies as it enables the carbon-free production of fuels and chemicals through renewable electricity. Here, chemical transformations require only mild conditions of temperature and pressure as they are driven by charge transfer at the solid-liquid interface.

One of the key objectives of the team´s research is to elucidate catalyst selectivity, the origin of which often remains poorly understood especially in the field of electrocatalysis.

This analysis focuses on a microscopic mechanism where a certain reaction intermediate escapes the catalyst surface to be detected as an early, partially-converted product. A new, multi-scale kinetic model shows how selectivity depends upon the rate of species’ transport through the electrolyte and quantifies the influence from the density of catalytically active sites, also known as catalyst roughness. Despite its simplicity, the model is able to reproduce a series of trends found in the experimental literature.

This result demonstrates the generality of the proposed mechanism and establishes roughness as a key descriptor of catalyst morphology across all relevant length scales.The insight improves fundamental understanding of reaction mechanisms in electrocatalysis, while suggesting new paths ahead for optimizing catalyst selectivity and long-term operation.