An effective method for improving energy storage performance in (Bi0.5Na0.5)TiO3-based lead-free relaxor ferroelectrics

Next-generation advanced high/pulsed power capacitors urgently require dielectric materials with outstanding energy storage performance. (Bi_0.5Na_0.5)TiO₃-based material, a typical lead-free ferroelectrics, has the characteristics of high polarization strength and excellent component compatibility, making it emerge as a potential candidate for energy storage applications.

Researchers have made an interesting breakthrough in the modification of the BNT-based ferroelectrics, an effective method for various properties such as relaxor features and energy storage performance. The new method utilizes a high-entropy concept to create A-site BNT-based high-entropy relaxor ferroelectrics, and add B-site disorder on this basis, which can further improve the ion disorder to reduce short-range order. Thus, it is easier to form isolated and weak coupled polar nanoclusters in the dielectric matrix. This characteristic makes it obtain a high relaxor feature and delayed saturation polarization under an electric field, which is beneficial for good energy storage performance. This represents an important advancement over existing methods.

The traditional approach to creating relaxor ferroelectrics (RFEs), which normally relies on doping heterogeneous ions to cause local compositional inhomogeneity and ion disorder to obtain polar nanoregions (PNRs). “But the solid solubility is limited, even though BNT has good component compatibility,” Neng-Neng Luo, the leader of the research team said, “the Gibbs phase rule tells us it is hard to further improve the ion disorder and relaxor feature by chemical doping.”

This method overcomes this limitation by constructing a high entropy single-phase solid solution. Meanwhile, on the basis of the A-site disorder, an additional B-site disorder further breaks the size of PNRs and weakens the coupling between PNRs. The highly broken and weak coupled PNRs may restrict their growth into micro-domains under high electric fields, thereby leading to slimmer P–E loops and further prolonged polarization saturation.

This innovation not only provides new ideas for the design of ferroelectric materials, but proves that a B-site modification strategy based on the A-site high-entropy disorder is also an effective way of improving energy storage density. Additionally, it could explain the domain change process of ferroelectric energy storage ceramics under an electric field.

Meanwhile, the research team is optimistic about the application of their work. They believe that the method, requiring no complex fabrication processes, could readily be achieved inhigh energy storage density with ultra-high efficiency.

The team published their work in Journal of Advanced Ceramics on 14 March, 2024.

This is an important development in the field of dielectric energy storage materials, and its potential applications are vast. The researchers’ work highlights the power of combining advanced materials with innovative design concepts to achieve breakthroughs with far-reaching consequences.

This work was supported by the Guangxi Natural Science Fund for Distinguished Young Scholars (Grant No. 2022GXNSFFA035034), National Natural Science Foundation of China (Grant Nos. 52072080 and U22A20127), and National Key Research and Development Program of China (Grant No. 2022YFC2408600).

About the Authors

Dr. Nengneng Luo is a professor in School of Resources, Environment and Materials, Guangxi University. He received his PhD degree in Chemistry from Tsinghua University in 2015. He studied at the Pennsylvania State University as a joint-training PhD student from 2013 to 2014. His research activity is focused on designing novel high-performance lead-free (anti)ferroelectric materials and their application for energy storage/piezoelectric sensor, and finding the correlations between microstructure (such as crystal structure, domain wall, defect, etc.) and physical performance.

Miss Kaihua Yang is a master graduate student of School of Resources, Environment and Materials, Guangxi University. Her research focuses on developing new lead-free ferroelectric materials for energy storage applications.

About Journal of Advanced Ceramics

Journal of Advanced Ceramics (JAC) is an international journal that presents the state-of-the-art results of theoretical and experimental studies on the processing, structure, and properties of advanced ceramics and ceramic-based composites. JAC is Fully Open Access, monthly published by Tsinghua University Press on behalf of the State Key Laboratory of New Ceramics and Fine Processing (Tsinghua University) and the Advanced Ceramics Division of the Chinese Ceramic Society, and exclusively available via SciOpen. JAC has been indexed in SCIE (IF = 16.9, top 1/28, Q1), Scopus, and Ei Compendex.

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