To stick or not to stick? Mixed sand columns illuminate design of better materials

Tokyo, Japan – Scientists from Tokyo Metropolitan University have been studying the strength and toughness of sand columns made of a mixture of sticky and non-sticky grains. They have uncovered the mechanism behind how the strength changes as grains are mixed in different ratios, and how a mixture can help keep the column more resilient to deformation. Non-sticky grains are also easily replaceable with other materials, enabling the design of stronger, tougher, functional matter.

Granular matter consists of vast numbers of small grains, like sand and powders. Such grains can be made to stick to each other, yielding strong materials like concrete. But strength isn’t everything. Strong materials can be brittle, and easily crack when deformed. Science-driven design of materials which are not only stronger but tougher too continues to be a challenge for material scientists.

A team from Tokyo Metropolitan University led by Professor Rei Kurita have been studying the mechanical properties of sand columns, a simple yet powerful model for granular matter. Instead of focusing on grains which all stick to one another, they have been looking at mixtures of non-sticky normal sand and “kinetic” sand, silicone-oil coated grains which can stick to each other. While the mechanics of “attractive grains” is relatively well understood, that cannot be said for materials where stickiness only features in a subset of grains.

When they made columns with different proportions of sticky grains, they found that the strength of the column, as characterized by how much they deform when put under a load, shows a characteristic stepped change. When the proportion of sticky sand reaches 60%, the strength suddenly jumps to a higher value. More sticky sand does not lead to any further increase. Through computer simulations of a similar setup, they found that this was exactly when sticky grains formed a rigid network which extended through the sample. This needs to be distinguished from sticky grains simply connecting through the sample; lines of sticky grains, for example, can easily deform when the ends are pushed together. It is only when there are enough connections between grains that the sticky grains can support a weight.

Unlike typical strong materials however, these partially sticky columns show unique behavior when they are put under larger loads. As the column deforms, the columns don’t crack; they instead change their shape: the connections between sticky grains aren’t simply being destroyed but are able to rearrange and reform. This makes the columns not only strong, but tough.

The team note that since more than 60% sticky grains doesn’t change the strength, the other 40% can be easily switched with any other material, for example, something with antibacterial properties.  This counterintuitive design feature paves the way for composite materials which are not only stronger and tougher, but functional too.

This work was supported by JSPS KAKENHI Grant Numbers 17H02945, 20K14431, and 20H01874.