The preparation of M−NHC functionalized MOFs (IMAGE)
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To date, two synthetic approaches have been published for the preparation of M−NHC functionalized MOFs, and describe the direct self−assembly of M−NHC ligands with metal salts (Route 1) or the post synthetic modification (PSM) of imidazolium functionalized MOFs. The currently reported methods are incompatible with the characteristics of MOFs and consequently, development of a facile and general approach to prepare M−NHC functionalized MOFs for highly efficient heterogeneous catalysis is highly desirable.
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