关于配体支撑下该铁团簇电子结构的计算化学研究 (IMAGE) Science China Press Caption 计算化学研究表明中心原子和周围铁原子之间的作用是多中心铁铁键,而外围铁原子之间则是通过铁磁耦合相互作用。外围配体则通过Fe-S配位和W-Fe成键进一步稳定该[Fe@Fe12]团簇。 Credit ©《中国科学》杂志社 Usage Restrictions Use with credit. License Original content Disclaimer: AAAS and EurekAlert! are not responsible for the accuracy of news releases posted to EurekAlert! by contributing institutions or for the use of any information through the EurekAlert system.