Figure 1 (IMAGE) Institute for Basic Science Caption Scheme of a time-resolved serial femtosecond crystallography (TR-SFX) experiment on porous coordination network–224(Fe), PCN–224(Fe). The crystals of PCN–224(Fe) are exposed to an intense femtosecond UV laser pulse to trigger a reaction. Ultrafast structural changes of iron porphyrin and zirconium clusters in PCN–224(Fe) were directly visualized using X-ray pulses from the X-ray free-electron laser facility with femtosecond (10−15 second) and angstrom (10−10 meter) spatio-temporal resolution. By measuring the X-ray diffraction patterns produced by the X-ray pulses over time, the molecular structure of PCN–224(Fe) after the reaction was observed. Credit Institute for Basic Science Usage Restrictions Attribution Required License Original content Disclaimer: AAAS and EurekAlert! are not responsible for the accuracy of news releases posted to EurekAlert! by contributing institutions or for the use of any information through the EurekAlert system.