Figure 3 (IMAGE)
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Photoinduced trifurcating structural changes of PCN–224(Fe) observed by means of TR-SFX. Upon irradiation, one CO molecule dissociates from iron porphyrin and organized motions occur within 200 fs. The organized motions include the oscillatory motion (Iosc) and the formation of the transient structure (Itr). Furthermore, alongside the organized motions, the thermally hot structure (Ihot) emerges through random atomic movements.
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Institute for Basic Science
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