Public Release: 

Thermally activated delayed photoluminescence from semiconductor nanocrystals

North Carolina State University


IMAGE: Pyrenecarboxylic acid-functionalized CdSe quantum dots undergo thermally activated delayed photoluminescence. view more 

Credit: Cedric Mongin

Researchers from North Carolina State University have found that the transfer of triplet excitons from nanomaterials to molecules also creates a feedback mechanism that returns some energy to the nanocrystal, causing it to photoluminesce on long time scales. The mechanism can be adjusted to control the amount of energy transfer, which could be useful in optoelectronic applications.

Felix N. Castellano, Goodnight Innovation Distinguished Chair of Chemistry at NC State, had previously shown that semiconductor nanocrystals could transfer energy to molecules, thereby extending their excited state lifetimes long enough for them to be useful in photochemical reactions.

In a new contribution, Castellano and Cédric Mongin, a former postdoctoral researcher currently an assistant professor at École normale supérieure Paris-Saclay in France, have shown that not only does the transfer of triplet excitons extend excited state lifetimes, but also that some of the energy gets returned to the original nanomaterial in the process.

"When we looked at triplet exciton transfers from nanomaterials to molecules, we noticed that after the initial transfer the nanomaterial would still luminesce in a delayed fashion, which was unexpected," says Castellano. "So we decided to find out what exactly was happening at the molecular level."

Castellano and Mongin utilized cadmium selenide (CdSe) quantum dots as the nanomaterial and pyrenecarboxylic acid (PCA) as the acceptor molecule. At room temperature, they found that the close proximity of the relevant energy levels created a feedback mechanism that thermally repopulated the CdSe excited state, causing it to photoluminesce.

Taking the experiment one step further, the researchers then systematically varied the CdSe-PCA energy gap by changing the size of the nanocrystals. This resulted in predictable changes to the resultant excited state lifetimes. They also examined this process at different temperatures, yielding results consistent with a thermally activated energy transfer mechanism.

"Depending on relative energy separation, the system can be tuned to behave more like PCA or more like the CdSe nanoparticle," says Castellano. "It's a control dial for the system. We can make materials with unique photoluminescent properties simply by controlling the size of the nanoparticle and the temperature of the system."


The work appears in Nature Chemistry, and was supported by the Air Force Office of Scientific Research (FA9550-13-1-0106) and the U.S. Department of Energy (DE-SC0011979). Mongin is first author and Castellano is corresponding author. Pavel Moroz and Mikhail Zamkov of Bowling Green State University also contributed to the work.

Note to editors: An abstract of the paper follows.

"Thermally activated delayed photoluminescence from pyrenyl-functionalized CdSe quantum dots"

DOI: 10.1038/nchem.2906

Authors: Cédric Mongin, North Carolina State University and Laboratoire PPSM, France; Pavel Moroz and Mikhail Zamkov, Bowling Green State University; Felix Castellano, North Carolina State University

Published: Nature Chemistry


The generation and transfer of triplet excitons across semiconductor nanomaterial-molecular interfaces will play an important role in emerging photonic and optoelectronic technologies and understanding the rules that govern such phenomena is essential. The ability to cooperatively merge the photophysical properties of semiconductor quantum dots, with those of well-understood and inexpensive molecular chromophores is therefore paramount. Here we show that 1-pyrenecarboxylic acid (PCA)-functionalized CdSe quantum dots undergo thermally activated delayed photoluminescence. This phenomenon results from a near quantitative triplet-triplet energy transfer from the nanocrystals to PCA, producing a molecular triplet-state 'reservoir' that thermally repopulates the photoluminescent state of CdSe through endothermic reverse triplet-triplet energy transfer. The photoluminescence properties are systematically and predictably tuned through variation of the quantum dot-molecule energy gap, temperature, and the triplet-excited-state lifetime of the molecular adsorbate. The concepts developed here will likely be applicable to semiconductor nanocrystals interfaced with molecular chromophores enabling potential applications of their combined excited states.

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