Thiol ligands produce different higher-order nanocluster structures (IMAGE)
Caption
Two thiol ligands, SPhpOMe and SPhoMe, produce chiral, mirror-image gold-silver (Au9Ag6) nanocluster structures depending on the thiol ligand used during assembly. Clusters created using the SPhpOMe ligand form two variants that arrange in an ABAB higher-order superlattice pattern and clusters formed using the SPhoMe ligand form four variants that assemble in an ABCDABCD pattern.
Credit
Polyoxometalates, Tsinghua University Press
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