Dual-radical-based molecular anisotropy and synergy between magnetism and conductivity (IMAGE)
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Dual radicals were observed directionally for the first time in a semiconductive VT coordination polymer due to the presence of two crystallographically independent SQ•– radicals. The directional variations of these dual radicals, as well as their 180° periods were confirmed by the angle-dependent EPR spectroscopy. The conductive anomaly along the ab plane in the open-form complex is due to the electron transfer during the VT process.
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