Figure 1. Depletion Attraction used for Pickering Emulsion (IMAGE)
Caption
(a) Schematic illustration of particle adsorption to the interface by depletion attraction. (b) Photographs of compared emulsions (0.18?vol% of 1?μm-silica particles) formed with the presence of PEG (10,000?g?mol?1, left) and the absence of PEG (right), taken after several hours from voltex emulsification (?3,000?r.p.m.). Here, φ is the oil fraction of the initial oil-water mixture before emulsifying. Scale bar, 1?cm. (c) Photograph of φ=0.6 emulsion (0.18?vol% silica particles) with oil-soluble fluorescence dyes and its confocal micrograph. Scale bar, 100?μm. (d) Photograph of φ=0.8 high internal phase Pickering emulsion (0.18?vol% silica particles) and its confocal micrographs. Scale bar, 100?μm. (e) Confocal microscope image of fluorescently labelled silica particles (1.08?vol% silica particles) well adsorbed on an oil droplet surface by depletion attraction. Scale bar, 30?μm. All emulsions and HIPPEs (b-e) are produced by the vortexing method.
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