The PBC cube improves the cathode electrochemical performance, enhancing the power output and durability of the PCFC. (IMAGE)
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TME results show that the PBC particles are cubic and the {100} crystal planes are exposed on the surface. This gives rise to more surface oxygen vacancies and efficient Cu2+-O-Cu3+ electron-hopping transition paths, favoring high electrocatalytic activity with expeditious oxygen adsorption/activation, and facilitating the oxygen reduction reaction (ORR) process. The particle-cube PBC cathode assembled at 950 ℃ (PBC-950) exhibits significantly enhanced power density and excellent durability on PCFCs.
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Journal of Advanced Ceramics, Tsinghua University Press
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