TOC abstract (IMAGE) Shanghai Jiao Tong University Journal Center Caption A multifunctional Janus film is fabricated by integrating highly-crystalline and oxidation-resistant Ti3C2Tx MXene with carbon nanotube (CNT) film through strong hydrogen bonding, which exhibits high electrical conductivity of 4250 S cm−1 and robust mechanical strength of 77 MPa. The MXene/CNT Janus film of 15 μm thickness demonstrates efficient electromagnetic interference shielding of 72 dB, low infrared (IR) emissivity of 0.09 and hence superior thermal camouflage performance, and outstanding IR detection capability, while maintaining its integrity equally at room temperature as well as under extreme conditions. This multifunctional MXene/CNT Janus film offers a practical solution for electromagnetic shielding and IR shielding/detection in challenging conditions. Credit All authors Usage Restrictions Credit must be given to the creator. Only noncommercial uses of the work are permitted. No derivatives or adaptations of the work are permitted. License CC BY-NC-ND Disclaimer: AAAS and EurekAlert! are not responsible for the accuracy of news releases posted to EurekAlert! by contributing institutions or for the use of any information through the EurekAlert system.